CHRONICLE
Physical Metallurgy and Heat Treatment
The paper studies the statistical dependence of the mechanical properties of 218 forgings (15 types) made of VT3-1 and VT6 alloys in 2000–2014 on chemical composition (the content of alloying elements and admixtures, structural and strength equivalents of aluminum and molybdenum), structure types, subtypes and parameters after annealing, quenching and aging. It was found that the strength and plastic properties of one-type forgings vary quite widely. The share of variation of forging properties due to fluctuations in the content of main components and admixtures, as well as the influence of structure types and sizes of structural components was estimated.
Based on the correlation analysis it was revealed that the change of each alloying element or admixture content has a little or no effect on forging properties. This is caused by small increments of their change within the grade composition. However, their total content expressed in terms of aluminum and molybdenum equivalents can vary over a fairly wide range. It was statistically substantiated that the share of tensile strength variation of VT3-1 and VT6 forgings may be ~25÷65 % due to the influence of their chemical compositions (in terms of aluminum and molybdenum equivalents), and about 20 % due to only the influence of structure types and subtypes. When these two factors (composition + structure) are combined, the share of variation can reach ~50÷65 %. For plastic properties and impact toughness, this figure is less and ranges from 20 to 35 %. The mathematical models are offered to forecast the mechanical properties of forgings depending on the structure parameters and aluminum and molybdenum equivalents.
This paper is a continuation of studies on the effect of microalloying with gadolinium, a rare earth metal, on the structure formation and properties of a titanium alloy under thermal action. It was previously shown that the introduction of gadolinium into an experimental heat-resistant alloy promotes cast structure transformation and reduces the size of structural components, and affects the rate of growth and nucleation of particles. It has been established that additional alloying of gadolinium has no significant influence on the microstructure formation of hot-rolled sheets made of the heat-resistant experimental alloy after annealing at 950 °C. The structure is represented by equiaxial particles of the primary α-phase, secondary α-phase of lamellar morphology and a small amount of β-phase.
It has been established that the ordering processes occur in primary α-phase particles and α2-phase particles are formed during isothermal aging at 700 °C for 100 h with the formation of silicides at the α-β interface. It is shown that the α2 phase is formed in the body of the primary α-phase particles, and its border regions are free from precipitations that is due to their aluminum depletion as a result of β→α transformation. It has been established that the silicide particle size is reduced as the gadolinium content in the alloy increases. The average particle size is 0,2–0,3 μm in the alloy with 0 % Gd, and it is reduced to 0,05–0,1 μm in the alloy with 0,2 % Gd.
It was shown that the introduction of 0,2 % of gadolinium into the heat-resistant titanium alloy leads to a decrease in the gas-saturated layer depth, and to an increase in the cyclic durability and short-term strength at 700 °C by 30 %.
This paper examines the ZK51A (ML12) alloy samples with the content of Zn from 3.5 to 5.5 wt.% and Zr from 0.5 to 0.8 wt.%.
The influence of the Zn and Zr content on phase transition temperatures and phase composition in equilibrium conditions and with the Scheil-Gulliver solidification model was determined using the phase diagram calculation in Thermo-Calc software. It is shown that the Zr content of 0.8–0.9 wt.% leads to a significant increase in the alloy liquidus temperature and requires raising the melting temperature over 800 °С. This is undesirable when using steel crucibles. The equilibrium content of alloying elements in the magnesium solid solution was calculated at different temperatures. Scanning electron microscopy was used to study the microstructures of ascast and heat-treated alloys with different alloying elements content. The distribution of Zn and Zr in a dendritic cell of the alloy in as-cast and heat-treated conditions was investigated. Zinc in an as-cast condition is accumulated on the dendritic cell boundary, but after the heat treatment its concentration in the center of the dendritic cell became higher than concentration on the cell boundary.
Zirconium is accumulated in the center of the dendritic cell. We determined the effect of the solution heat treatment conditions on the alloy hardness. The maximum hardness gain was achieved using a two-step treatment at 330 °С for 5 h and then at 400 °С for 5 h. We studied the effect of aging heat treatment (150 and 200 °C) on the alloy hardness. The better hardness was achieved after aging at 200 °С. The maximum value was reached after 8–10 h of aging. The tensile strength 285 ± 13.5 MPa and elongation 11.4 ± 1 % were achieved after the two-step heat treatment consisting of isothermal holding at 330 °С for 5 h and then at 400 °С for 5 h with quenching and aging at 200 °С for 8 h.
ISSN 2412-8783 (Online)