PROBLEMS OF ANALYTICAL CONTROL IN PRODUCTION OF RARE AND PRECIOUS METALS
https://doi.org/10.17073/0021-3438-2018-3-19-35
Abstract
The article focuses on one of the important issues in rare and precious metals industry development – analytical control. It reviews the current state, importance, problems and prospects for analytical control development as an integral part of the rare and precious metal production and product quality assurance. Modern analytical control methods are described, namely atomic spectral, mass spectral, X-ray fluorescent and combined ones as well as their rational applications. It is shown that scientific and technological progress is inextricably linked with a drastic increase in the nomenclature of materials based on rare and precious metals and higher requirements for their quality. This will require creating new and improving existing analytical control methods, their standardization and metrological support. This work should involve research organizations in theRussianAcademy of Sciences, universities, industry research centers with research laboratories that have survived in the country after theSoviet Union dissolution, as well as promote plant research activities. It is necessary to effectively use the achievements of advanced analytical laboratories abroad, participate in international comparative tests. At the same time, special attention is paid to unsolved problems – scientifically justified statement of requirements for new types of products based on rare and precious metals; development and metrological assessment of sampling methods; development of high-quality metrological support for analytical control of rare and precious metal production; improvement of analytical methods; standardization of analytical methods; accreditation of analytical laboratories; training of highly qualified analytical chemists.
About the Authors
Yu. A. KarpovRussian Federation
Acad. of RAS, Dr. Sci. (Chem.), chief research scientist of Chemical Analysis Laboratory of IGIC RAS, professor of Department Certification and Analytical Control of NUST «MISIS»
119991, Russia, Moscow, Leninskii pr., 31
V. B. Baranovskaya
Russian Federation
Dr. Sci. (Chem.), leading scientist of Chemical Analysis Laboratory of IGIC RAS, associate prof. of Department of Certification and Analytical Control of NUST «MISIS»
119991, Russia, Moscow, Leninskii pr., 31
References
1. Sazhin N.P. Redkie elementy i tekhnicheskii progress [Rare elements and technical progress]. Moscow: Znanie, 1967.
2. Giredmet — 70 let v metallurgii redkikh metallov i poluprovodnikov [Giredmet — 70 years in metallurgy of rare metals and semiconductors]. Collection of articles. Moscow: OIT TsINAO, 2001.
3. Shelagurov V. Pochemu redki u nas redkie metally [That is why rare metals are rare ours]. Metally Evrazii. 2005. No. 6. P. 60—63.
4. Kosynkin V.D., Glebov V.A. Vozrozhdenie rossiiskogo proizvodstva redkozemel’nykh metallov — vazhneishaya zadacha otechestvennoi ekonomiki. In: Funktsional’nye nanomaterialy i vysokochistye veshchestva: Mater. III Mezhdunarodnoi konferentsii [The revival of the Russian production of rare-earth metals is the most important task of the domestic economy. In: Functional materials and high purity substances: Proc. Mater. III Intern. Conf. (Suzdal, 4—8 Oct. 2010)]. Moscow: IMET RAN, 2010. P. 10
5. Melent’ev G. Redkie zemli Rossii: Perspektivy i prioritety [Rare earths of Russia: Perspectives and priorities]. Redkie zemli. 2015. No. 1(4). P. 56—60.
6. Alimarin I.P., Yakovlev Yu.D. Yaderno-fizicheskie metody analiza. In: Yaderno-fizicheskie metody analiza veshchestva [Nuclear physical methods of analysis. In: Nuclear physical methods of substance’ analysis]. Moscow: Atomizdat, 1971. P. 5—14.
7. Parkhomenko Yu.N., Karpov Yu.A., Baranovskaya V.B. Chistye redkie i dragotsennye metally — pod kontrolem TsKP instituta «Giredmet» [Pure rare and precious metals under the control of CKP of Giredmet institute]. Nanotekhnologii. Ekologiya. Proizvodstvo. 2013. No. 3 (22). P. 28—29.
8. Kotlyar Yu.A., Meretukov M.A., Strizhko L.S. Metallurgiya blagorodnykh metallov [Metallurgy of precious metals]. Vol. 2. Moscow: Izd. dom «Ruda i metally», 2005.
9. Strizhko L.S., Loleit S.I. Izvlechenie tsvetnykh i blagorodnykh metallov iz elektronnogo loma [Extraction of non-ferrous and precious metals from electronic scrap]. Moscow: Izd. dom «Ruda i metally», 2009.
10. Problemy pererabotki «elektronnogo» loma, soderzhashchego dragotsennye metally: Obz. Informatsiya [The problems of processing «electronic» scrap containing precious metals: Overview information]. No. 2. Moscow: Rosvtordragmet, 1995.
11. Karpov Yu.A., Savostin A.P., Sal’nikov V.D. Analiticheskii kontrol’ v metallurgicheskom proizvodstve [Analytical control in metallurgical production]. Moscow: IKTs «Akademkniga», 2006.
12. Losev N.F., Smagunova A.N. Osnovy rentgenospektral’nogo fluorestsentnogo analiza [Fundamentals of X-Ray fluorescence analysis]. Moscow: Khimiya, 1982.
13. Aisueva T.S., Finkel’shtein A.L., Belozerova O.Yu., Skornikova S.A. Rentgenofluorestsentnoe opredelenie platiny, reniya, palladiya v katalizatorakh na osnove oksida alyuminiya [X-ray fluorescence determination of platinum, rhenium, palladium in catalysts based on aluminum oxide] . Analitika i kontrol’. 2014. Vol. 18. No. 4. P. 411—417.
14. Shabanova L.N., Obrazovskii E.G., Akulova G.I., Sryvtseva T.B. Probootbor i opredelenie blagorodnykh metallov v tekhnologicheskikh produktakh i otkhodakh proizvodstva. In: Analitika Sibiri i Dal’nego Vostoka — 2004: Mater. VII konf. [Sampling and determination of precious metals in process and waste products. In: Analytics of Siberia and the Far East — 2004: Mater. VII Conf. (Novosibirsk, 11—16 Oct. 2004)]. Novosibirsk: Izd-vo Instituta kataliza SO RAN, 2004. P. 96.
15. Shestakov V.A., Arkhipov N.A., Makarov D.F., Kukushkin Yu.N. Rentgenospektral’nyi analiz shlamov i platinovykh kontsentratov na blagorodnye metally [X-ray spectral analysis of slimes and platinum concentrates for precious metals]. Zhurnal analiticheskoi khimii. 1974. Vol. 29. No. 12. P. 2176—2180.
16. Antonova Yu.V., Bukhryakov V.A., Karpov Yu.A., Lyamina O.I., Kupriyanova T.A., Filippov M.N. Direct X-ray fluorescence determination of platinum and rhodium in used ceramic-based autocatalysts. Inorg. Mater. 2014. Vol. 50. No. 14. P. 1431—1434.
17. Obrazovskii E.G., Akulova G.I., Sryvtseva T.B. Kompleksnyi podkhod k analizu katalizatorov, soderzhashchikh dragotsennye metally, i produktov ikh pererabotki. In: Analitika Sibiri i Dal’nego Vostoka — 2004: Mater. VII konf. [An integrated approach to the analysis of catalysts containing precious metals and their products. In: Analytics of iberia and the Far East — 2004: Mater. VII Conf. (Novosibirsk, 11—16 Oct. 2004)]. Novosibirsk: Izd-vo Instituta kataliza SO RAN, 2004. P. 97.
18. Shestakov V.A., Malofeeva G.I., Petrukhin O.M., Marcheva E.V., Esenova N.K., Murinov Yu.I., Nikitin Yu.E., Zolotov Yu.A. Sorbtsionno-rentgenofluorestsentnoe opredelenie tyazhelykh metallov s ispol’zovaniem polimernogo tioefira [Sorption-X-ray fluorescence determination of heavy metals using a polymeric thioether]. Zhurnal analiticheskoi khimii. 1983. Vol. 38. No. 12. P. 2131—2136.
19. Oskolok K.V., Monogarova O.V., Alov N.V. Opredelenie ko bal’ta i rtuti v vode metodom rentgenofluorestsentnogo analiza v rezhime polnogo vneshnego otrazheniya s predvaritel’nym kontsentrirovaniem na penopoliuretanovom sorbente [Total-reflection X-ray fluorescence determination of cobalt and mercury in water using preconcentration on a polyurethane foam sorbent]. Vestnik Moskovskogo universiteta. Ser. 2. Khimiya. 2014. Vol. 55. No. 4. P. 203—206.
20. Analiticheskaya khimiya metallov platinovoi gruppy [Analytical chemistry of platinum group metals: Collection of articles]. Eds. Yu.A. Zolotov, G.M. Varshal, V.M. Ivanov. Moscow: Editorial URSS, 2003.
21. Puig A.I., Alvarado J.I. Evaluation of four sample treatments for determination of platinum in automotive catalytic converters by graphite furnace atomic absorption spectrometry. Spectrochim. Acta. Part B. 2006. Vol. 61. P. 1050—1053.
22. Dal’nova O.A., Shiryaeva O.A., Karpov Yu.A., Alekseeva T.Yu., Shiryaev A.A., Kulikauskas V.S., Filatova D.G. Pryamoe atomno-absorbtsionnoe opredelenie platiny, palladiya i rodiya v otrabotannykh avtokatalizatorakh na keramicheskoi osnove [Direct atomic-absorption determination of platinum, palladium and rhodium in spent ceramic autocatalysts]. Zavodskaya laboratoriya. Diagnostika materialov. 2009. Vol. 75. No. 7. P. 3—7.
23. Kulikova L.D., Shiryaeva O.A., Karpov Yu.A. Atomnoabsorbtsionnoe opredelenie platiny, palladiya i rodiya v avtomobil’nykh katalizatorakh [Atomic absorption determination of platinum, palladium and rhodium in automotive catalysts]. Latv. Kim. Z. 2003. No. 2. Р. 154—158.
24. Stafilov T. Determination of trace elements in minerals by electrothermal atomic absorption spectrometry. Spectrochim. Acta. Part B. 2000. Vol. 55. No. 7. Р. 893—906.
25. Nazarenko I.I., Kislova I.V., Kashina L.I., Bakhareva T.V., Malofeeva G.I., Petrukhin O.M., Murinov Yu.I., Zolotov Yu.A. Atomno-absorbtsionnoe opredelenie rtuti v vodakh posle sorbtsionnogo kontsentrirovaniya na polimernom tioefire [Atomic absorption determination of mercury in waters after sorption concentration on a polymeric thioether]. Zhurnal analiticheskoi khimii. 1986. Vol. 29. No. 8. P. 1385—1389.
26. Castillo J.R., Lopez.-Molinero A., Sucunza T. Determination of As, Sb and Bi in high-purity copper by electrothermal atomic absorption spectrometry. Microchim. Acta. 1986. Vol. 35. No. 4. P. 330—332.
27. Savel’eva A.N., Agapova T.E. Opredelenie mysh’yaka v mednykh sernokislykh elektrolitakh i elektrolitnoi medi metodom elektrotermicheskoi atomno-absorbtsionnoi spektrometrii [Determination of arsenic in copper sulphate electrolytes and electrolyte copper by electrothermal atomic absorption spectrometry]. Zavodskaya laboratoriya. 1990. Vol. 56. No. 4. P. 40—42.
28. Mullen J.D. Determination of arsenic in high-purity copper by flameless atomic-absorption spectrophotometry. Talanta. 1977. Vol. 24. No. 10. P. 657—658.
29. D’yachkova A.V., Malyutina T.M., Alekseeva T.Yu., Karpov Yu.A. Khimicheskaya podgotovka prob otrabotannykh avtomobil’nykh katalizatorov dlya posleduyushchego opredeleniya platiny, palladiya i rodiya metodom atomno-emissionnoi spektrometrii s induktivno-svyazannoi plazmoi [Chemical preparation of samples of spent automotive catalysts for the subsequent determination of platinum, palladium and rhodium by inductively coupled plasma atomic emission spectrometry]. Zavodskaya laboratoriya. Diagnostika materialov. 2011. Vol. 77. No. 6. P. 3—9.
30. OST 153-39.2-032-2003 Otrabotannye katalizatory alyumoplatinovye monometallicheskie i polimetallicheskie i otkhody proizvodstva katalizatorov [Spent catalysts are aluminoplatinum monometallic and polymetallic and waste products of catalysts.]. Moscow: Ministerstvo energetiki Rossiiskoi Federatsii, 2003.
31. TU 64-5-103-89 Katalizator palladievyi otrabotannyi. Tekhnicheskie usloviya [Palladium spent catalyst. Specifications]. Moscow: Ministerstvo meditsinskoi promyshlennosti USSR, 1989.
32. Kubrakova I.V., Myasoedova G.V., Shumskaya T.V., Kudinova T.F., Zakharchenko E.A., Mokhodoeva O.B. Opredelenie sledov blagorodnykh metallov v prirodnykh ob”ektakh kombinirovannymi metodami [Determination of trace noble metals in natural samples using hyphenated methods]. Zhurnal analiticheskoi khimii. 2005. Vol. 60. No. 5. P. 536—539.
33. Filichkina V.A., Alekseeva T.Yu., Chemleva T.A., Karpov Yu.A., Miskar’yants V.G. Razrabotka metodiki atomno-emissionnogo s induktivno svyazannoi plazmoi opredeleniya platinovykh metallov v shamotnykh otkhodakh s avtoklavnoi probopodgotovkoi i planirovaniem eksperimenta [Development of the technique of atomic emission with inductively coupled plasma determination of platinum metals in fireclay waste with autoclave sample preparation and experiment planning]. Zavodskaya laboratoriya. Diagnostika materialov. 2011. Vol. 77. No. 2. P. 11—15.
34. Golubova E.A., Loseva M.P. Ispol’zovanie atomno-emissionnogo plazmennogo spektrometra SPECTRO CIROS v analize materialov, soderzhashchikh platinovye metally [Use of the SPECTRO CIROS atomic emission plasma spectrometer in the analysis of materials containing platinum metals]. Analitika i kontrol’. 2003. Vol. 7. No. 2. P. 182—183.
35. Peter S. Doidge. Determination of trace impurities in high-purity copper by sequential ICP-OES with axial viewing. Agilent Technologies, Inc., USA, 2010. ICPES-25.
36. Savkina V.N., Dolganyuk I.M., Peikhvasser N.N., Ivleva N.M., Saprykina N.N., Proskurina L.P. Ispol’zovanie atomno-emissionnogo metoda s induktivno svyazannoi plazmoi dlya kontrolya primesnykh elementov v produktakh metallurgicheskogo proizvodstva OEMK [Use of the atomic-emission method with inductively coupled plasma to control impurity elements in metallurgical products of OEMK]. Analitika i kontrol’. 2004. Vol. 8. No. 1. P. 51—55.
37. Glinskaya I.V., Gorbunov V.B., Podgorodetskii G.S., Teselkina A.E. Analiticheskii kontrol’ metallurgicheskogo protsessa pererabotki krasnogo shlama [Analytical control of metallurgical processing of red mud]. Izv. vuzov. Cher. metallurgiya. 2013. No. 9. P. 17—21.
38. Khil’ko A.A., Simonyan L.M., Glinskaya I.V., Teselkina A.E. Osobennosti izucheniya sostava elektrostaleplavil’noi pyli [Features of studying the composition of electric steelmaking dust]. Izv. vuzov. Cher. metallurgiya. 2014. No. 1. P. 9—13.
39. George C.-Y. Chan, Gary M. Hieftje. Investigation of plasma-related matrix effects in inductively coupled plasma-atomic emission spectrometry caused by matrices with low second ionization potentials — identification of the secondary factor. Spectrochim. Acta. Pt. B. 2006. Vol. 61. Р. 642—659.
40. Britske M.E. Atomno-absorbtsionnyi spektrokhimicheskii analiz [Atomic absorption spectrochemical analysis]. Moscow: Khimiya, 1982.
41. Pohl P., Zyrnicki W. Study of chemical and spectral interferences in the simultaneous determination of As, Bi, Sb, Se and Sn by hydride generation inductively coupled plasma atomic emission spectrometry. Anal. Chim. Acta. 2002. Vol. 468. P. 71—79.
42. Thomas R. Practical Guide to ICP-MS (Practical Spectroscopy). Marcel Dekker, 2004.
43. Doronina M.S., Karpov Yu.A., Baranovskaya V.B., Loleit S.I. Vozvratnoe metallosoderzhashchee syr’e — obshchaya kharakteristika i klassifikatsiya dlya tselei sertifikatsii [Recyclable metal-containing raw materials a general characteristic and classification for certification]. Zavodskaya laboratoriya. Diagnostika materialov. 2016. Vol. 82. No. 6. P. 70—80.
44. Karpov Yu.A., Baranovskaya V.B. Analiticheskaja sluzhba v Rossii: istoki i perspektivy [Analytical service in Russia: sources and prospects]. Metody otsenki sootvetstviya. 2011. No. 5. P. 6—9.
Review
For citations:
Karpov Yu.A., Baranovskaya V.B. PROBLEMS OF ANALYTICAL CONTROL IN PRODUCTION OF RARE AND PRECIOUS METALS. Izvestiya. Non-Ferrous Metallurgy. 2018;(3):19-35. (In Russ.) https://doi.org/10.17073/0021-3438-2018-3-19-35