INFLUENCE OF IMPURITIES IN ELECTROLYTE (USING THE EXAMPLE OF TIN, GERMANIUM, AND ANTIMONY) ON CURRENT EFFICIENCY OF ZINC
https://doi.org/10.17073/0021-3438-2014-3-237-238
Abstract
There was investigated influence tin, germanium and antimony, as well as animal glue on the current yield (η) and specific energy consumption during zinc electrolysis. There were received adequate regression models of dependences of η and W on cathode current density and animal glue in electrolyte at constant temperature. There were defined ranks of independent variables according with intensity of influence on η value. They are distributed in cluster in the following way (according with decreasing of impact): Ge, Sn, Sb. There was empirically established that antimony in the range of 0,001–0,150 mg/l increases the current efficiency of zinc.
About the Authors
V. M. AlkatsevRussian Federation
M. I. Alkatsev
Russian Federation
V. A. Linkov
Russian Federation
I. V. Darchiev
Russian Federation
References
1. Mackinnon D.J., Fenn P.L. // J. Appl. Electrochem. 1984. Vol. 14, № 6. Р. 401.
2. Алкацев М.И., Алкацев В.М., Дарчиев И.В. // Сб. докл. 4-го Междунар. конгр. «Цветные металлы-2012» (Красноярск, 5—7 сент. 2012 г.). Красноярск: Версо, 2012. С. 135.
3. Liebscher R. // Neue Hutte. 1969. Bd 14, № 11. S. 651.
4. Баймаков Ю.В., Журин А.И. Электролиз в гидрометаллургии. М.: Металлургия, 1977.
Review
For citations:
Alkatsev V.M., Alkatsev M.I., Linkov V.A., Darchiev I.V. INFLUENCE OF IMPURITIES IN ELECTROLYTE (USING THE EXAMPLE OF TIN, GERMANIUM, AND ANTIMONY) ON CURRENT EFFICIENCY OF ZINC. Izvestiya. Non-Ferrous Metallurgy. 2014;(3):20-24. (In Russ.) https://doi.org/10.17073/0021-3438-2014-3-237-238