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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">cvmet</journal-id><journal-title-group><journal-title xml:lang="ru">Известия вузов. Цветная металлургия</journal-title><trans-title-group xml:lang="en"><trans-title>Izvestiya. Non-Ferrous Metallurgy</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0021-3438</issn><issn pub-type="epub">2412-8783</issn><publisher><publisher-name>НИТУ "МИСИС"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17073/0021-3438-2015-6-43-52</article-id><article-id custom-type="elpub" pub-id-type="custom">cvmet-275</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Металловедение и термическая обработка</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Physical Metallurgy and Heat Treatment</subject></subj-group></article-categories><title-group><article-title>ОБЪЕМНЫЕ МЕТАЛЛИЧЕСКИЕ СТЕКЛА: ПОЛУЧЕНИЕ, СТРУКТУРА, СТРУКТУРНЫЕ ИЗМЕНЕНИЯ ПРИ НАГРЕВЕ</article-title><trans-title-group xml:lang="en"><trans-title>Bulk metallic glasses: fabrication, structure, and structural changes under heating</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Лузгин</surname><given-names>Д. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Louzguine</surname><given-names>D. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>докт. техн. наук, профессор Университета Тохоку (2-1-1 Катахира, Аоба-ку, Сендай, 980-8577, Япония).</p></bio><bio xml:lang="en"><p>Dr. Sci. (Eng.), Prof., WPI Advanced Institute for Materials Research, Tohoku University (2-1-1 Katahira, Aoba-Ku, Sendai, 980-8577, Japan)</p></bio><email xlink:type="simple">dml@wpi-aimr.tohoku.ac.jp</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Полькин</surname><given-names>В. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Pol’kin</surname><given-names>V. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. техн. наук, доцент кафедры «Технология и оборудование трубного производства» МИСиС (119049, г. Москва, Ленинский пр., 4)</p></bio><bio xml:lang="en"><p>Cand. Sci. (Eng.), Assistant Prof., National University of Science and Technology «MISIS» (119049, Russia, Moscow, Leninsky prospect, 4)</p></bio><email xlink:type="simple">vipolkin@gmail.com</email><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff xml:lang="ru" id="aff-1"><institution>WPI-AIMR, Университет Тохоку, Япония</institution><country>Russian Federation</country></aff><aff xml:lang="ru" id="aff-2"><institution>Национальный исследовательский технологический университет «МИСиС», г. Москва</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2015</year></pub-date><pub-date pub-type="epub"><day>17</day><month>12</month><year>2015</year></pub-date><volume>0</volume><issue>6</issue><fpage>43</fpage><lpage>52</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Лузгин Д.В., Полькин В.И., 2015</copyright-statement><copyright-year>2015</copyright-year><copyright-holder xml:lang="ru">Лузгин Д.В., Полькин В.И.</copyright-holder><copyright-holder xml:lang="en">Louzguine D.V., Pol’kin V.I.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://cvmet.misis.ru/jour/article/view/275">https://cvmet.misis.ru/jour/article/view/275</self-uri><abstract><p>Объемные металлические стекла (ОМС) систем Pd–Cu–Si и Pd–Ni–P были получены из расплава в 70–80-х годах прошлого века. Однако ввиду исключительной дороговизны основного компонента (палладия) они долгое время не представляли особого интереса для ученых и инженеров. Относительно недавно ОМС в виде слитков макроскопического размера были получены в сплавах на основе промышленных металлов (железа, меди, магния и титана), что открыло широкие возможности для их применения. ОМС обладают высокими показателями прочности, твердости, износостойкости, упругой деформации и сопротивления коррозии. В настоящей работе приведен обзор литературных источников и описаны основные научные достижения в данной области. Отмечено что главными, не до конца решенными научными проблемами являются описания структуры ОМС, а также процессов стеклования и пластической деформации, а технической задачей, приковывающей внимание ученых разных стран, – повышение пластичности и ударной вязкости данных материалов.</p></abstract><trans-abstract xml:lang="en"><p>Bulk metallic glasses (BMGs) of Pd–Cu–Si and Pd–Ni–P system were formed from the melt in 1970s–1980s. However, in view of the extremely high cost of the main component (palladium), they were out of special interest for scientists and engineers for a long time. Relatively recently, BMGs in a form of macroscopic-size ingots here fabricated in alloys based on industrial metals (iron, copper, magnesium, and titanium), which opened wide possibilities for their application. BMGs possess high strength, hardness, wear resistance, elastic deformation, and corrosion resistance. In this study, a review of publications is presented and main scientific achievements in this field are described. It is noted that main scientific problems, which are not solved completely, are the description of the BMG structure as well as vitrification and plastic deformation, while the technical problem, which attracts attention of scientists in many countries, is an increase in plasticity and impact fracture toughness of these materials.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>объемные металлические стекла</kwd><kwd>структура</kwd><kwd>стеклование</kwd><kwd>прочность</kwd><kwd>пластичность</kwd></kwd-group><kwd-group xml:lang="en"><kwd>bulk metallic glasses</kwd><kwd>structure</kwd><kwd>vitrification</kwd><kwd>strength</kwd><kwd>ductility</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Buckel W., Hilsch R. Einflub der Kondensation bei tiefen temperaturen auf den elektrischen widerstand und die supraleitung für verschiedene metalle. Z. Phys. 1954. Bd. 138. S. 109—120.</mixed-citation><mixed-citation xml:lang="en">Buckel W., Hilsch R. Einflub der Kondensation bei tiefen temperaturen auf den elektrischen widerstand und die supraleitung für verschiedene metalle. Z. Phys. 1954. Bd. 138. S. 109—120.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Klement W., Willens R. H., Duwez P. Non-crystalline structure in solidified Gold-Silicon alloys. Nature. 1967. Vol. 187. P. 869.</mixed-citation><mixed-citation xml:lang="en">Klement W., Willens R. H., Duwez P. Non-crystalline structure in solidified Gold-Silicon alloys. Nature. 1967. Vol. 187. P. 869.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Angell C.A. Structural instability and relaxation in liquid and glassy phases near the fragile liquid limit. J. Non-Cryst. Solids. 1988. Vol. 102. P. 205.</mixed-citation><mixed-citation xml:lang="en">Angell C.A. Structural instability and relaxation in liquid and glassy phases near the fragile liquid limit. J. Non-Cryst. Solids. 1988. Vol. 102. P. 205.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Chen H.S. Thermodynamic consideration on the formation and stability of metallic glass. Acta Metall. 1974. Vol. 22. P. 1505.</mixed-citation><mixed-citation xml:lang="en">Chen H.S. Thermodynamic consideration on the formation and stability of metallic glass. Acta Metall. 1974. Vol. 22. P. 1505.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Kui H. W., Greer A. L., Turnbull D. Formation of Bulk Metallic-Glass by Fluxing. Appl. Phys. Lett. 1984. Vol. 45. P. 615.</mixed-citation><mixed-citation xml:lang="en">Kui H. W., Greer A. L., Turnbull D. Formation of Bulk Metallic-Glass by Fluxing. Appl. Phys. Lett. 1984. Vol. 45. P. 615.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Inoue A. Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 2000. Vol. 48. P. 279.</mixed-citation><mixed-citation xml:lang="en">Inoue A. Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 2000. Vol. 48. P. 279.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Johnson W.L. Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 1999. Vol. 24. P. 42.</mixed-citation><mixed-citation xml:lang="en">Johnson W.L. Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 1999. Vol. 24. P. 42.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Чердынцев В.В., Калошкин С.Д., Томилин И.А. Взаимодействие порошка железа с кислородом воздуха при механоактивации // ФММ. 1998. T. 86. No. 6. C. 84—89; Cherdyncev V.V., Kaloshkin S.D., Tomilin I.A. Vzaimodejstvie poroshka zheleza s kislorodom vozduha pri mehanoaktivacii [Iron powder interaction with air oxygen at mechanoactivation]. Fizika metallov i metallovedenie. 1998. Vol. 86. No. 6. P. 84—89.</mixed-citation><mixed-citation xml:lang="en">Чердынцев В.В., Калошкин С.Д., Томилин И.А. Взаимодействие порошка железа с кислородом воздуха при механоактивации // ФММ. 1998. T. 86. No. 6. C. 84—89; Cherdyncev V.V., Kaloshkin S.D., Tomilin I.A. Vzaimodejstvie poroshka zheleza s kislorodom vozduha pri mehanoaktivacii [Iron powder interaction with air oxygen at mechanoactivation]. Fizika metallov i metallovedenie. 1998. Vol. 86. No. 6. P. 84—89.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Глезер А.М., Сундеев Р.В., Шалимова А.В. Склонность металлических кристаллов к аморфизации в процессе мегапластической (интенсивной) деформации // Доклады Академии наук. 2012. Т. 447. No. 2. Р. 158—161; Glezer A.M., Sundeev R.V., Shalimova A.V. Sklonnost’ metallicheskikh kristallov k amorfizatsii v protsesse megaplasticheskoi (intensivnoi) deformatsii [The tendency of metal crystals to amorphization in megaplastic (intensive) strain]. Doklady Akademii nauk. 2012. Vol. 447. No. 2. P. 158—161.</mixed-citation><mixed-citation xml:lang="en">Глезер А.М., Сундеев Р.В., Шалимова А.В. Склонность металлических кристаллов к аморфизации в процессе мегапластической (интенсивной) деформации // Доклады Академии наук. 2012. Т. 447. No. 2. Р. 158—161; Glezer A.M., Sundeev R.V., Shalimova A.V. Sklonnost’ metallicheskikh kristallov k amorfizatsii v protsesse megaplasticheskoi (intensivnoi) deformatsii [The tendency of metal crystals to amorphization in megaplastic (intensive) strain]. Doklady Akademii nauk. 2012. Vol. 447. No. 2. P. 158—161.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Yamasaki T., Schlossmacher P., Ehrlich K., Ogino Y. Formation of amorphous electrodeposited Ni—W alloys and their nanocrystallization. Nanostruct. Mater. 1998. Vol. 10. P. 375.</mixed-citation><mixed-citation xml:lang="en">Yamasaki T., Schlossmacher P., Ehrlich K., Ogino Y. Formation of amorphous electrodeposited Ni—W alloys and their nanocrystallization. Nanostruct. Mater. 1998. Vol. 10. P. 375.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Бражкин В.В., Волошин Р.Н., Ляпин А.Г., Попова С.В. Квазипереходы в простых жидкостях при высоких давлениях // УФН. 1999. T. 169. C. 1035—1039; Brazhkin V.V., Voloshin R.N., Ljapin A.G., Popova S.V. Kvaziperehody v prostyh zhidkostjah pri vysokih davlenijah [Quasitransitions in simple liquids with high pressures]. Uspehi fiz. nauk. 1999. Vol. 169. Р. 1035—1039.</mixed-citation><mixed-citation xml:lang="en">Бражкин В.В., Волошин Р.Н., Ляпин А.Г., Попова С.В. Квазипереходы в простых жидкостях при высоких давлениях // УФН. 1999. T. 169. C. 1035—1039; Brazhkin V.V., Voloshin R.N., Ljapin A.G., Popova S.V. Kvaziperehody v prostyh zhidkostjah pri vysokih davlenijah [Quasitransitions in simple liquids with high pressures]. Uspehi fiz. nauk. 1999. Vol. 169. Р. 1035—1039.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Matsubara E., Waseda Y. Structural studies of new metallic amorphous alloys with wide supercooled liquid region. Mater. Trans. JIM. 1995. Vol. 36. P. 883.</mixed-citation><mixed-citation xml:lang="en">Matsubara E., Waseda Y. Structural studies of new metallic amorphous alloys with wide supercooled liquid region. Mater. Trans. JIM. 1995. Vol. 36. P. 883.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Antonowicz J., Georgarakis K., Vaughan G., Yavari A. R., Inoue A. Real-space structural studies of Cu—Zr—Ti glassy alloy. J. Alloys Comp. 2008. Vol. 466. P. 106.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Antonowicz J., Georgarakis K., Vaughan G., Yavari A. R., Inoue A. Real-space structural studies of Cu—Zr—Ti glassy alloy. J. Alloys Comp. 2008. Vol. 466. P. 106.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Bernal J.D. Geometry of the Structure of Monoatomic Liquids. Nature. 1960. Vol. 185. P. 68.</mixed-citation><mixed-citation xml:lang="en">Bernal J.D. Geometry of the Structure of Monoatomic Liquids. Nature. 1960. Vol. 185. P. 68.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Miracle D.B. The efficient cluster packing model — An atomic structural model for metallic glasses. Acta Mater. 2006. Vol. 54. P. 4317.</mixed-citation><mixed-citation xml:lang="en">Miracle D.B. The efficient cluster packing model — An atomic structural model for metallic glasses. Acta Mater. 2006. Vol. 54. P. 4317.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Sheng H.W., Luo W.K., Alamgir F.M., Bai J.M., Ma E. Atomic packing and short-to-medium-range order in metallic glasses. Nature. 2006. Vol. 439. P. 419.</mixed-citation><mixed-citation xml:lang="en">Sheng H.W., Luo W.K., Alamgir F.M., Bai J.M., Ma E. Atomic packing and short-to-medium-range order in metallic glasses. Nature. 2006. Vol. 439. P. 419.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Oreshkin A.I., Mantsevich V.N., Savinov S.V., Oreshkin S.I., Panov V.I., Maslova N.S., Louzguine-Luzgin D.V. Direct visualization of Ni—Nb bulk metallic glasses surface: From initial nucleation to full crystallization. Appl. Phys. Lett. 2012. Vol. 101. No. 18. P. 181601.</mixed-citation><mixed-citation xml:lang="en">Oreshkin A.I., Mantsevich V.N., Savinov S.V., Oreshkin S.I., Panov V.I., Maslova N.S., Louzguine-Luzgin D.V. Direct visualization of Ni—Nb bulk metallic glasses surface: From initial nucleation to full crystallization. Appl. Phys. Lett. 2012. Vol. 101. No. 18. P. 181601.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Hirata A., Kang L.J., Fujita T., Klumov B., Matsue K., Kotani M., Yavari A.R., Chen M.W. Direct observation of local atomic order in a metallic glass. Science. 2013. Vol. 341. P. 376—379.</mixed-citation><mixed-citation xml:lang="en">Hirata A., Kang L.J., Fujita T., Klumov B., Matsue K., Kotani M., Yavari A.R., Chen M.W. Direct observation of local atomic order in a metallic glass. Science. 2013. Vol. 341. P. 376—379.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Hirata A., Hirotsu Y., Ohkubo T., Tanaka N., Nieh T.G. Local atomic structure of Pd—Ni—P bulk metallic glass investigated by high-resolution electron microscopy and electron diffraction. Intermetallics. 2006. Vol. 14. No.8-9. P. 903.</mixed-citation><mixed-citation xml:lang="en">Hirata A., Hirotsu Y., Ohkubo T., Tanaka N., Nieh T.G. Local atomic structure of Pd—Ni—P bulk metallic glass investigated by high-resolution electron microscopy and electron diffraction. Intermetallics. 2006. Vol. 14. No.8-9. P. 903.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Yavari A.R., Vaughan G., Inoue A. Clustered crystalline structures as glassy phase approximants. Intermetallics. 2009. Vol. 17. No. 7. P. 477—480.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Yavari A.R., Vaughan G., Inoue A. Clustered crystalline structures as glassy phase approximants. Intermetallics. 2009. Vol. 17. No. 7. P. 477—480.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Belosludov R., Yavari A.R., Georgarakis K., Vaughan G., Kawazoe Y., Egami T., Inoue А. Structural basis for supercooled liquid fragility established by synchrotron-radiation method and computer simulation. J. Appl. Phys. 2011. Vol. 110 . P. 043519.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Belosludov R., Yavari A.R., Georgarakis K., Vaughan G., Kawazoe Y., Egami T., Inoue А. Structural basis for supercooled liquid fragility established by synchrotron-radiation method and computer simulation. J. Appl. Phys. 2011. Vol. 110 . P. 043519.</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Sheng H., Liu H., Cheng Y., Wen J., Lee P.L, Luo W., Shast-ri S.D., Ma E. Polyamorphism in a metallic glass. Nat. Mater. 2007. Vol. 6. P. 192 .</mixed-citation><mixed-citation xml:lang="en">Sheng H., Liu H., Cheng Y., Wen J., Lee P.L, Luo W., Shast-ri S.D., Ma E. Polyamorphism in a metallic glass. Nat. Mater. 2007. Vol. 6. P. 192 .</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Wada T., Kato H., Perepezko J., Inoue A. In situ phase separation and flow behavior in the glass transition region. Intermetallics. 2010 . Vol. 18. Nо. 6. P. 1235 - 1239.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Wada T., Kato H., Perepezko J., Inoue A. In situ phase separation and flow behavior in the glass transition region. Intermetallics. 2010 . Vol. 18. Nо. 6. P. 1235 - 1239.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Seki I., Yamamoto T., Kawaji H., Suryanarayana C., Inoue A. Double-stage glass transition in a metallic glass. Phys. Rev. B. 2010. Vol. 81. P. 144202.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Seki I., Yamamoto T., Kawaji H., Suryanarayana C., Inoue A. Double-stage glass transition in a metallic glass. Phys. Rev. B. 2010. Vol. 81. P. 144202.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Cohen M.H., Grest G.S. Liquid-glass transition: a free volume approach. Phys. Rew. 1979. Vol. 20. P. 1077.</mixed-citation><mixed-citation xml:lang="en">Cohen M.H., Grest G.S. Liquid-glass transition: a free volume approach. Phys. Rew. 1979. Vol. 20. P. 1077.</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Beukel A. Van Den, Sietsma J. The glass transition as a free volume related kinetic phenomenon. Acta Metall. Mater. 1990. Vol. 38. P. 383.</mixed-citation><mixed-citation xml:lang="en">Beukel A. Van Den, Sietsma J. The glass transition as a free volume related kinetic phenomenon. Acta Metall. Mater. 1990. Vol. 38. P. 383.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Kauzmann W. The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures. Chem. Rev. 1948. Vol. 43. P. 219.</mixed-citation><mixed-citation xml:lang="en">Kauzmann W. The Nature of the Glassy State and the Behavior of Liquids at Low Temperatures. Chem. Rev. 1948. Vol. 43. P. 219.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Inoue A. The outline of glass transition phenomenon derived from the viewpoint of devitrification process. Physics and Chemistry of Glasses: Eur. J. Glass. Sci. Technol. Pt. B. 2009. Vol. 50. Nо. 1. Р. 27—30.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Inoue A. The outline of glass transition phenomenon derived from the viewpoint of devitrification process. Physics and Chemistry of Glasses: Eur. J. Glass. Sci. Technol. Pt. B. 2009. Vol. 50. Nо. 1. Р. 27—30.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Molokanov V.V., Petrzhik M.I., Mikhailova T.N., Sviridova T.A., Djakonova N.P. Formation of bulk (Zr,Ti)-based metallic glasses. J. Non-Cryst. Solids. 1999. Vol. 250—252. P. 560—565.</mixed-citation><mixed-citation xml:lang="en">Molokanov V.V., Petrzhik M.I., Mikhailova T.N., Sviridova T.A., Djakonova N.P. Formation of bulk (Zr,Ti)-based metallic glasses. J. Non-Cryst. Solids. 1999. Vol. 250—252. P. 560—565.</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Miracle D.B., Louzguina-Luzgina L., Inoue A. Comparative analysis of glass-formation in binary, ternary, and multicomponent alloys. J. Appl. Phys. 2010. Vol. 108. P. 103511.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Miracle D.B., Louzguina-Luzgina L., Inoue A. Comparative analysis of glass-formation in binary, ternary, and multicomponent alloys. J. Appl. Phys. 2010. Vol. 108. P. 103511.</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Angell C.A. Formation of glasses from liquids and biopolymers. Science. 1995. Vol. 2. P. 1924—1935.</mixed-citation><mixed-citation xml:lang="en">Angell C.A. Formation of glasses from liquids and biopolymers. Science. 1995. Vol. 2. P. 1924—1935.</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Senkov O. Correlation between fragility and glass-forming ability of metallic alloys. Phys. Rev. 2007. Vol. 76. P. 104—202 .</mixed-citation><mixed-citation xml:lang="en">Senkov O. Correlation between fragility and glass-forming ability of metallic alloys. Phys. Rev. 2007. Vol. 76. P. 104—202 .</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V. Vitrification and devitrification processes in metallic glasses. J. Alloys Comp. 2014. Vol. 586. P. 2—8.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V. Vitrification and devitrification processes in metallic glasses. J. Alloys Comp. 2014. Vol. 586. P. 2—8.</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Belosludov R., Saito M., Kawazoe Y., Inoue A. Glass-transition behavior of Ni: Calculation, prediction, and experiment. J. Appl. Phys. 2008. Vol. 104. Р. 123529.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Belosludov R., Saito M., Kawazoe Y., Inoue A. Glass-transition behavior of Ni: Calculation, prediction, and experiment. J. Appl. Phys. 2008. Vol. 104. Р. 123529.</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Novikov V.N., Sokolov A.P. Poisson’s ratio and fragility of glass-forming liquids. Nature. 2004. Vol. 431. P. 961.</mixed-citation><mixed-citation xml:lang="en">Novikov V.N., Sokolov A.P. Poisson’s ratio and fragility of glass-forming liquids. Nature. 2004. Vol. 431. P. 961.</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Lu Z.P., Liu C.T. A new glass-forming ability criterion for bulk metallic glasses. Acta. Mater. 2002. Vol. 50. P. 3501 .</mixed-citation><mixed-citation xml:lang="en">Lu Z.P., Liu C.T. A new glass-forming ability criterion for bulk metallic glasses. Acta. Mater. 2002. Vol. 50. P. 3501 .</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Suryanarayana C., Seki I., Inoue A. A critical analysis of the glass-forming ability of alloys. J. Non-Cryst. Solids. 2009. Vol. 355. P. 355—360.</mixed-citation><mixed-citation xml:lang="en">Suryanarayana C., Seki I., Inoue A. A critical analysis of the glass-forming ability of alloys. J. Non-Cryst. Solids. 2009. Vol. 355. P. 355—360.</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Nishiyama N., Inoue A. Direct comparison between critical cooling rate and some quantitative parameters for evalua tion of glass-forming ability in Pd—Cu—Ni—P alloys. Mater. Trans. 2002. Vol. 43. P. 1913.</mixed-citation><mixed-citation xml:lang="en">Nishiyama N., Inoue A. Direct comparison between critical cooling rate and some quantitative parameters for evalua tion of glass-forming ability in Pd—Cu—Ni—P alloys. Mater. Trans. 2002. Vol. 43. P. 1913.</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Yavari A.R. Small volume change on melting as a new criterion for easy formation of metallic glasses. Phys. Lett. A. 1983. Vol. 95. P. 165.</mixed-citation><mixed-citation xml:lang="en">Yavari A.R. Small volume change on melting as a new criterion for easy formation of metallic glasses. Phys. Lett. A. 1983. Vol. 95. P. 165.</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Inoue A. An extended criterion for estimation of glass-forming ability of metals. J. Mater. Res. 2007. Vol. 22 P. 1378—1383.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Inoue A. An extended criterion for estimation of glass-forming ability of metals. J. Mater. Res. 2007. Vol. 22 P. 1378—1383.</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Setyawan A.D., Kato H., Inoue A. Thermal conductivity of an alloy in relation to the observed cooling rate and glass-forming ability. Philosoph. Magazine. 2007. Vol. 87. P. 1845—1854.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Setyawan A.D., Kato H., Inoue A. Thermal conductivity of an alloy in relation to the observed cooling rate and glass-forming ability. Philosoph. Magazine. 2007. Vol. 87. P. 1845—1854.</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Inoue A. Electronegativity of the constituent rare-earth metals as a factor stabilizing the supercooled liquid region in Al- based metallic glasses. Appl. Phys. Lett. 2001. Vol. 79. P. 3410.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Inoue A. Electronegativity of the constituent rare-earth metals as a factor stabilizing the supercooled liquid region in Al- based metallic glasses. Appl. Phys. Lett. 2001. Vol. 79. P. 3410.</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Egami T., Waseda Y. Atomic size effect on the formability ofmetallic glasses. J. Non-Cryst. Solids. 1984. Vol. 64. P. 113.</mixed-citation><mixed-citation xml:lang="en">Egami T., Waseda Y. Atomic size effect on the formability ofmetallic glasses. J. Non-Cryst. Solids. 1984. Vol. 64. P. 113.</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Jiang Q., Chi B.Q., Li J.C. A valence electron concentration criterion for glass-formation ability of metallic liquids. Appl. Phys. Lett. 2003. Vol. 82. P. 2984 .</mixed-citation><mixed-citation xml:lang="en">Jiang Q., Chi B.Q., Li J.C. A valence electron concentration criterion for glass-formation ability of metallic liquids. Appl. Phys. Lett. 2003. Vol. 82. P. 2984 .</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">Debenedetti P.G., Stillinger F.H. Supercooled liquids and the glass transition. Nature. 2001. Vol. 410. P. 259.</mixed-citation><mixed-citation xml:lang="en">Debenedetti P.G., Stillinger F.H. Supercooled liquids and the glass transition. Nature. 2001. Vol. 410. P. 259.</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Inoue A., Saito M., Waseda Y. Structural relaxation in Ge—Cr—Al—Nd amorphous alloy. Scripta Mater. 2000. Vol. 42. Nо. 3. P. 289—294.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Inoue A., Saito M., Waseda Y. Structural relaxation in Ge—Cr—Al—Nd amorphous alloy. Scripta Mater. 2000. Vol. 42. Nо. 3. P. 289—294.</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">Busch R. The thermophysical properties of bulk metallic glass-forming liquids. JOM. 2000. Vol. 52. P. 39.</mixed-citation><mixed-citation xml:lang="en">Busch R. The thermophysical properties of bulk metallic glass-forming liquids. JOM. 2000. Vol. 52. P. 39.</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Лысенко А.В., Ляхов С.А., Хоник В.А., Язвицкий М.Ю. Сдвиговая вязкость металлического стекла Pd40Cu40P20 в условиях изохронного нагрева ниже температуры стеклования // Физика твердого тела. 2009. T. 51. C. 209; Lysenko A.V., Ljahov S.A., Honik V.A., Jazvickij M.Ju. Sdvigovaja vjazkost’ metallicheskogo stekla Pd40Cu40P20 v uslovijah izohronnogo nagreva nizhe temperatury steklovanija [Shift viscosity of metal Pd40Cu40P20 glass in the conditions of isochronous heating is lower than vitrification temperature]. Fizika tverdogo tela. 2009. Vol. 51. P. 209.</mixed-citation><mixed-citation xml:lang="en">Лысенко А.В., Ляхов С.А., Хоник В.А., Язвицкий М.Ю. Сдвиговая вязкость металлического стекла Pd40Cu40P20 в условиях изохронного нагрева ниже температуры стеклования // Физика твердого тела. 2009. T. 51. C. 209; Lysenko A.V., Ljahov S.A., Honik V.A., Jazvickij M.Ju. Sdvigovaja vjazkost’ metallicheskogo stekla Pd40Cu40P20 v uslovijah izohronnogo nagreva nizhe temperatury steklovanija [Shift viscosity of metal Pd40Cu40P20 glass in the conditions of isochronous heating is lower than vitrification temperature]. Fizika tverdogo tela. 2009. Vol. 51. P. 209.</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Aljerf M., Georgarakisa K., Yavari A.R. Shaping of metallic glasses by stress-annealing without thermal embrittlement. Acta Mater. 2011. Vol. 59. P. 3817.</mixed-citation><mixed-citation xml:lang="en">Aljerf M., Georgarakisa K., Yavari A.R. Shaping of metallic glasses by stress-annealing without thermal embrittlement. Acta Mater. 2011. Vol. 59. P. 3817.</mixed-citation></citation-alternatives></ref><ref id="cit50"><label>50</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Ko M.S., Inoue A. Nanoscale icosahedral phase produced by devitrification of Hf—Au—Ni—Al and Hf—Au—Cu—Al metallic glasses. Scripta Mater. 2001. Vol. 44. Р. 637—642.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Ko M.S., Inoue A. Nanoscale icosahedral phase produced by devitrification of Hf—Au—Ni—Al and Hf—Au—Cu—Al metallic glasses. Scripta Mater. 2001. Vol. 44. Р. 637—642.</mixed-citation></citation-alternatives></ref><ref id="cit51"><label>51</label><citation-alternatives><mixed-citation xml:lang="ru">Абросимова Г.Е., Аронин А.С., Зверькова И.И. Фазовые превращения при кристаллизации аморфных сплавов Al—Ni—Re // ФММ. 2002. Т. 94. С. 1—6; Abrosimova G.E., Aronin A.S., Zver’kova I.I. Fazovye prevrashcheniya pri kristallizatsii amorfnykh splavov Al—Ni—Re [Phase transformations at crystallization of amorphous alloys of Al—Ni—Re]. Fizika metallov i metallovedenie. 2002. Vol. 94. P.1—6.</mixed-citation><mixed-citation xml:lang="en">Абросимова Г.Е., Аронин А.С., Зверькова И.И. Фазовые превращения при кристаллизации аморфных сплавов Al—Ni—Re // ФММ. 2002. Т. 94. С. 1—6; Abrosimova G.E., Aronin A.S., Zver’kova I.I. Fazovye prevrashcheniya pri kristallizatsii amorfnykh splavov Al—Ni—Re [Phase transformations at crystallization of amorphous alloys of Al—Ni—Re]. Fizika metallov i metallovedenie. 2002. Vol. 94. P.1—6.</mixed-citation></citation-alternatives></ref><ref id="cit52"><label>52</label><citation-alternatives><mixed-citation xml:lang="ru">Greer A.L. Metallic glasses. Science. 1995. Vol. 267. P. 1947.</mixed-citation><mixed-citation xml:lang="en">Greer A.L. Metallic glasses. Science. 1995. Vol. 267. P. 1947.</mixed-citation></citation-alternatives></ref><ref id="cit53"><label>53</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Inoue A. Influence of a supercooled liquid on devitrification of Cu-, Hf- and Ni- based metallic glasses. Mater. Sci. Eng. A. 2004. Vol. 375—377. P. 346.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Inoue A. Influence of a supercooled liquid on devitrification of Cu-, Hf- and Ni- based metallic glasses. Mater. Sci. Eng. A. 2004. Vol. 375—377. P. 346.</mixed-citation></citation-alternatives></ref><ref id="cit54"><label>54</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Inoue A. Crystallization behaviour of Al-based metallic glasses below and above the glass-transition temperature. J. Non-Cryst. Solids. 2002. Vol. 311. Nо. 3. P. 281—293.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Inoue A. Crystallization behaviour of Al-based metallic glasses below and above the glass-transition temperature. J. Non-Cryst. Solids. 2002. Vol. 311. Nо. 3. P. 281—293.</mixed-citation></citation-alternatives></ref><ref id="cit55"><label>55</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Inoue A. Crystallization behavior of Ti50Ni25Cu25 amorphous alloy. J. Mater. Sci. 2000. Vol. 35. Nо. 16 . P. 4159—4164.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Inoue A. Crystallization behavior of Ti50Ni25Cu25 amorphous alloy. J. Mater. Sci. 2000. Vol. 35. Nо. 16 . P. 4159—4164.</mixed-citation></citation-alternatives></ref><ref id="cit56"><label>56</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Inoue A. Nanoparticles with icosahedral symmetry in Cu-based bulk glass former induced by Pd addition. Scripta Mater. 2003. Vol. 48. P. 1325.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Inoue A. Nanoparticles with icosahedral symmetry in Cu-based bulk glass former induced by Pd addition. Scripta Mater. 2003. Vol. 48. P. 1325.</mixed-citation></citation-alternatives></ref><ref id="cit57"><label>57</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Xie G., Zhang Q., Inoue A. Effect of Fe on the glass-forming ability, structure and devitrification behavior of Zr—Cu—Al bulk glass-forming alloys. Philosoph. Magazine. 2010. Vol. 90. Nо. 14. P. 1955—1968.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Xie G., Zhang Q., Inoue A. Effect of Fe on the glass-forming ability, structure and devitrification behavior of Zr—Cu—Al bulk glass-forming alloys. Philosoph. Magazine. 2010. Vol. 90. Nо. 14. P. 1955—1968.</mixed-citation></citation-alternatives></ref><ref id="cit58"><label>58</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Kaloshkin S.D., Inoue A. Peritectic-Like Reactions Involving Glassy Phase. Rev. Advan. Mater. Sci. 2008. Vol. 18. P. 653—659.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Kaloshkin S.D., Inoue A. Peritectic-Like Reactions Involving Glassy Phase. Rev. Advan. Mater. Sci. 2008. Vol. 18. P. 653—659.</mixed-citation></citation-alternatives></ref><ref id="cit59"><label>59</label><citation-alternatives><mixed-citation xml:lang="ru">Kim D.H., Kim W.T., Park E.S., Mattern N., Eckert J. Phase separation in metallic glasses. Progr. Mater. Sci. 2013. Vol. 58. P. 1103—1172.</mixed-citation><mixed-citation xml:lang="en">Kim D.H., Kim W.T., Park E.S., Mattern N., Eckert J. Phase separation in metallic glasses. Progr. Mater. Sci. 2013. Vol. 58. P. 1103—1172.</mixed-citation></citation-alternatives></ref><ref id="cit60"><label>60</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Wada T., Kato H., Perepezko J., Inoue A. In situ phase separation and flow behavior in the glass transition region. Intermetallics. 2010. Vol. 18. Nо. 6. P. 1235—1239.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Wada T., Kato H., Perepezko J., Inoue A. In situ phase separation and flow behavior in the glass transition region. Intermetallics. 2010. Vol. 18. Nо. 6. P. 1235—1239.</mixed-citation></citation-alternatives></ref><ref id="cit61"><label>61</label><citation-alternatives><mixed-citation xml:lang="ru">Perepezko J.H., Hebert R.J. Amorphous aluminum alloys—synthesis and stability. J. Metall. 2002. Vol. 54. P. 34.</mixed-citation><mixed-citation xml:lang="en">Perepezko J.H., Hebert R.J. Amorphous aluminum alloys—synthesis and stability. J. Metall. 2002. Vol. 54. P. 34.</mixed-citation></citation-alternatives></ref><ref id="cit62"><label>62</label><citation-alternatives><mixed-citation xml:lang="ru">Колмогоров А.Н. К статистической теории кристаллизации металлов // Изв. АН СССР. Сер. Матем. 1937. Т. 3. С. 355; Kolmogorov A.N. K statisticheskoi teorii kristallizatsii metallov [On the statistical theory of crystallization of metals]. Izv. Akad. Nauk. USSR. Ser. Matem. 1937. Vol. 3. P. 355.</mixed-citation><mixed-citation xml:lang="en">Колмогоров А.Н. К статистической теории кристаллизации металлов // Изв. АН СССР. Сер. Матем. 1937. Т. 3. С. 355; Kolmogorov A.N. K statisticheskoi teorii kristallizatsii metallov [On the statistical theory of crystallization of metals]. Izv. Akad. Nauk. USSR. Ser. Matem. 1937. Vol. 3. P. 355.</mixed-citation></citation-alternatives></ref><ref id="cit63"><label>63</label><citation-alternatives><mixed-citation xml:lang="ru">Johnson M.W.A., Mehl K.F. Reaction kinetics in processes of nucleation and growth. Trans. Amer. Inst. Mining. Met. Eng. 1939. Vol. 135. P. 416.</mixed-citation><mixed-citation xml:lang="en">Johnson M.W.A., Mehl K.F. Reaction kinetics in processes of nucleation and growth. Trans. Amer. Inst. Mining. Met. Eng. 1939. Vol. 135. P. 416.</mixed-citation></citation-alternatives></ref><ref id="cit64"><label>64</label><citation-alternatives><mixed-citation xml:lang="ru">Avrami M. Kinetics of phase change III: granulation, phase change an microstructures. J. Chem. Phys. 1941. Vol. 9. P. 177.</mixed-citation><mixed-citation xml:lang="en">Avrami M. Kinetics of phase change III: granulation, phase change an microstructures. J. Chem. Phys. 1941. Vol. 9. P. 177.</mixed-citation></citation-alternatives></ref><ref id="cit65"><label>65</label><citation-alternatives><mixed-citation xml:lang="ru">Hono K., Hiraga K., Wang Q., Inoue A., Sakurai T. The microstructure evolution of a Fe73,5Si13,5B9Nb3Cu1 nanocrystalline soft magnetic material. Acta. Metall. Mater. 1992. Vol. 40. P. 2137.</mixed-citation><mixed-citation xml:lang="en">Hono K., Hiraga K., Wang Q., Inoue A., Sakurai T. The microstructure evolution of a Fe73,5Si13,5B9Nb3Cu1 nanocrystalline soft magnetic material. Acta. Metall. Mater. 1992. Vol. 40. P. 2137.</mixed-citation></citation-alternatives></ref><ref id="cit66"><label>66</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Inoue A. Nanocrystallization of Ti—Ni— Sn amorphous alloy. Scripta Mater. 2000. Vol. 43. P. 371.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Inoue A. Nanocrystallization of Ti—Ni— Sn amorphous alloy. Scripta Mater. 2000. Vol. 43. P. 371.</mixed-citation></citation-alternatives></ref><ref id="cit67"><label>67</label><citation-alternatives><mixed-citation xml:lang="ru">He G., Eckert J., Loser W. Stability, phase transformation and deformation behavior of Ti-base metallic glass and composites. Acta Mater. 2003. Vol. 51. P. 1621.</mixed-citation><mixed-citation xml:lang="en">He G., Eckert J., Loser W. Stability, phase transformation and deformation behavior of Ti-base metallic glass and composites. Acta Mater. 2003. Vol. 51. P. 1621.</mixed-citation></citation-alternatives></ref><ref id="cit68"><label>68</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Kato H., Kim H.S., Inoue A. Formation of 2—5 nm size pre-precipitates of cF96 phase in a Hf—Co—Al glassy alloy. J. Alloys Compoun. 2003. Vol. 359. P. 198—201.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Kato H., Kim H.S., Inoue A. Formation of 2—5 nm size pre-precipitates of cF96 phase in a Hf—Co—Al glassy alloy. J. Alloys Compoun. 2003. Vol. 359. P. 198—201.</mixed-citation></citation-alternatives></ref><ref id="cit69"><label>69</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Suryanarayana C., Saito T., Zhang Q., Chen N., Saida J., Inoue A. Unusual solidification behavior of a Zr—Cu—Ni—Al bulk glassy alloy made from low-purity Zr. Intermetallics. 2010. Vol. 18. No. 8. P. 1531.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Suryanarayana C., Saito T., Zhang Q., Chen N., Saida J., Inoue A. Unusual solidification behavior of a Zr—Cu—Ni—Al bulk glassy alloy made from low-purity Zr. Intermetallics. 2010. Vol. 18. No. 8. P. 1531.</mixed-citation></citation-alternatives></ref><ref id="cit70"><label>70</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine D.V., Louzguina L.V., Inoue A. Multistage devitrification of Mg—Ni—Mm and Mg—Ni—Y—Mm metallic glasses (Mm = mischmetal). Philosoph. Magazine. 2003. Vol. 83. P. 203.</mixed-citation><mixed-citation xml:lang="en">Louzguine D.V., Louzguina L.V., Inoue A. Multistage devitrification of Mg—Ni—Mm and Mg—Ni—Y—Mm metallic glasses (Mm = mischmetal). Philosoph. Magazine. 2003. Vol. 83. P. 203.</mixed-citation></citation-alternatives></ref><ref id="cit71"><label>71</label><citation-alternatives><mixed-citation xml:lang="ru">Shechtman D., Blech L.A, Gratias D., Cahn J.W. Metallic phase with long-range orientational order and no translational symmetry. Phys. Rev. Lett. 1984. Vol. 53. P. 1951.</mixed-citation><mixed-citation xml:lang="en">Shechtman D., Blech L.A, Gratias D., Cahn J.W. Metallic phase with long-range orientational order and no translational symmetry. Phys. Rev. Lett. 1984. Vol. 53. P. 1951.</mixed-citation></citation-alternatives></ref><ref id="cit72"><label>72</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Inoue A. Formation and properties of quasicrystals. Ann. Rev. Mater. Res. 2008. Vol. 38. P. 403—423.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Inoue A. Formation and properties of quasicrystals. Ann. Rev. Mater. Res. 2008. Vol. 38. P. 403—423.</mixed-citation></citation-alternatives></ref><ref id="cit73"><label>73</label><citation-alternatives><mixed-citation xml:lang="ru">Kelton K.F., Gangopadhyay A.K., Lee G.W, Hannet L,. Hyers R.W., Krishnan S., Robinson M.B., Rogers J., Rathz T.J. Xray and electrostatic levitation undercooling studies in Ti— Zr—Ni quasicrystal forming alloys. J. Non-Cryst. Solids. 2002. Vol. 312—314. P. 305.</mixed-citation><mixed-citation xml:lang="en">Kelton K.F., Gangopadhyay A.K., Lee G.W, Hannet L,. Hyers R.W., Krishnan S., Robinson M.B., Rogers J., Rathz T.J. Xray and electrostatic levitation undercooling studies in Ti— Zr—Ni quasicrystal forming alloys. J. Non-Cryst. Solids. 2002. Vol. 312—314. P. 305.</mixed-citation></citation-alternatives></ref><ref id="cit74"><label>74</label><citation-alternatives><mixed-citation xml:lang="ru">Louzguine-Luzgin D.V., Zeng Y., Setyawan A.D.H., Nishiyama N., Kato H., Saida J, Inoue A. Deformation behavior of Zr- and Ni-based bulk glassy alloys. J. Mater. Res. 2007. Vol. 22. P. 1087.</mixed-citation><mixed-citation xml:lang="en">Louzguine-Luzgin D.V., Zeng Y., Setyawan A.D.H., Nishiyama N., Kato H., Saida J, Inoue A. Deformation behavior of Zr- and Ni-based bulk glassy alloys. J. Mater. Res. 2007. Vol. 22. P. 1087.</mixed-citation></citation-alternatives></ref><ref id="cit75"><label>75</label><citation-alternatives><mixed-citation xml:lang="ru">Glezer A.M., Sundeev R.V., Shalimova A.V., Useinov S.S. Tendency of metallic crystals to amorphization in the process of severe (Megaplastic) deformation. Russ. Phys. J. 2012. Vol. 54. P. 898—905.</mixed-citation><mixed-citation xml:lang="en">Glezer A.M., Sundeev R.V., Shalimova A.V., Useinov S.S. Tendency of metallic crystals to amorphization in the process of severe (Megaplastic) deformation. Russ. Phys. J. 2012. Vol. 54. P. 898—905.</mixed-citation></citation-alternatives></ref><ref id="cit76"><label>76</label><citation-alternatives><mixed-citation xml:lang="ru">Oak J.J., Louzguine-Luzgin D.V., Inoue A. Investigation of glass-forming ability, deformation and corrosion behavior of Ni-free Ti-based BMG alloys designed for application as dental implants. Mater. Sci. Eng. C. 2009. Vol. 29. Nо. 1. P. 322—327.</mixed-citation><mixed-citation xml:lang="en">Oak J.J., Louzguine-Luzgin D.V., Inoue A. Investigation of glass-forming ability, deformation and corrosion behavior of Ni-free Ti-based BMG alloys designed for application as dental implants. Mater. Sci. Eng. C. 2009. Vol. 29. Nо. 1. P. 322—327.</mixed-citation></citation-alternatives></ref><ref id="cit77"><label>77</label><citation-alternatives><mixed-citation xml:lang="ru">Caron A., Kawashima A., Fecht H.J., Louzguine-Luzguin D.V., Inoue А. On the anelasticity and strain induced structural changes in a Zr-based bulk metallic glass. Appl. Phys. Lett. 2011. Vol. 99. P. 171907.</mixed-citation><mixed-citation xml:lang="en">Caron A., Kawashima A., Fecht H.J., Louzguine-Luzguin D.V., Inoue А. On the anelasticity and strain induced structural changes in a Zr-based bulk metallic glass. Appl. Phys. Lett. 2011. Vol. 99. P. 171907.</mixed-citation></citation-alternatives></ref><ref id="cit78"><label>78</label><citation-alternatives><mixed-citation xml:lang="ru">Churyumov A.Yu., Bazlov A.I., Zadorozhnyy V.Yu., Solonin A.N., Caron A., Louzguine-Luzgin D.V. Phase transformations in Zr-based bulk metallic glass cyclically loaded before plastic yielding. Mater. Sci. Eng. A. 2012. Vol. 550. P. 358—362.</mixed-citation><mixed-citation xml:lang="en">Churyumov A.Yu., Bazlov A.I., Zadorozhnyy V.Yu., Solonin A.N., Caron A., Louzguine-Luzgin D.V. Phase transformations in Zr-based bulk metallic glass cyclically loaded before plastic yielding. Mater. Sci. Eng. A. 2012. Vol. 550. P. 358—362.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
